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Element synthesis up to 56Fe occurs in main sequence stars.
Elements heavier than Fe are synthesized in supernovae:
The solar system and the earth are around 4.6 billion years old.
The oldest rocks on earth date back to 3.8 - 4.0 billion years.
Original atmosphere on earth 'reducing': CO2, N2, H2, CO, H2O + trace amounts of NH3, CH4 (Oparin, Haldane).
Energy input - UV, cosmic rays, radioactivity etc. on the early earth:
The experiments of Stanley Miller:
Abiogenic synthesis of most 'building blocks' e.g. Strecker synthesis:
H2O RCHO + HCN + NH3 == RCH (NH2) CN -----> H2O RCH (NH2) CO - NH2 ----> RCH (NH2) COOH
Synthesis elsewhere in universe - Hoyle and Wickramasinghe.
Molecules in interstellar space - HCN, HCHO, H2NCN etc.
Ribozymes and the RNA world?
Catalytic function of RNA:
Membrane acquisition:
| ERA: | PERIOD: | EPOCH: | AGE (millions of years ago): | EVENTS: |
|---|---|---|---|---|
| Quaternary | Recent | 0.01 | Historic time | |
| Pleistoceine | 2.5 | Ice ages; humans appear | ||
| CENOZOIC | Tertiary | Pliocene | 7 | Ape-like ancestors of modern humans |
| Miocene | 25 | |||
| Oligocene | 38 | Origins of most modern mammals | ||
| Eocene | 54 | |||
| Paleocene | 65 | |||
| MESOZOIC | Cretaceous | 135 | Flowering plants appear; dinosaurs extinct | |
| Jurassic | 190 | Conifers, mammals & birds appear; dinosaurs dominant | ||
| Triassic | 235 | Mammal-like reptiles appear | ||
| Permian | 280 | Origin of most modern orders of insects | ||
| Carboniferous | 345 | Origin of reptiles; amphibians & bony fishes dominant; first seed plants | ||
| PALEOZOIC | Devonian | 395 | First land plants | |
| Silurian | 450 | |||
| Ordovician | 500 | First vertebrates | ||
| Cambrian | 570 | Origin of most invertebrates | ||
| PRECAMBRIAN | 4600 | Approximate age of the earth |
| |
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Stromatolites and the stromatolithic cherts.
Major Precambrian fossil sites:

Appearance of oxygen in the atmosphere - red beds.
Completion of element cycles.
Appearance of eukaryotes, 'acritarchs'.
Colonization of land.
HOW DID EUKARYOTES ARISE?
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